Journal of Organic Chemistry p. 15256 - 15267 (2018)
Update date:2022-08-04
Topics: Reaction mixture Transmetallation Workup and Isolation Oxidative Addition Reductive Elimination Preparation of the 1,1-dibromoolefin substrate Activation of the Pd Catalyst
Song, Xia
Gao, Cai
Zhang, Xinying
Fan, Xuesen
In this work, an unprecedented synthesis of (2H-chromen-2-ylidene)acetates and (2H-chromen-2-ylidene)ethanones with controlled stereoselectivity via Pd-catalyzed cascade reactions of 3-(2-(2,2-dibromovinyl)phenoxy)acrylates or 3-(2-(2,2-dibromovinyl)pheno
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