Synthesis of highly substituted 2-13c-imidazolium salts and metal NHC complexes for the investigation of electronic unsymmetry by NMR

DOI: 10.1055/s-0033-1338496

Source and publish data:

Synthesis p. 2251 - 2264 (2013)

Update date:2022-08-05

Topics:

Authors:

Emsermann, Jens

Arduengo, Anthonyj.

Opatz, Till

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1055/s-0033-1338496

Complexes of unsymmetrically substituted N-heterocyclic carbenes with NMR-active metals (Ag, Hg, Pt) with or without a ¹³C-label in the 2-position were synthesized by aldimine cross coupling and analyzed with respect to the scalar couplings between the metal center or C2 and the other ring atoms. Georg Thieme Verlag Stuttgart. New York.

Full text of DOI:10.1055/s-0033-1338496

Products guided by the article

Product name:(4-fluorophenyl)(propan-2-ylamino)acetonitrile

Cas No:1017679-76-3

R&D Labs maybe for 1017679-76-3

shanghai tuomiao chemicial co.,ltd.

website:https://www.tuomiaochem.com/

Contact:021 - 59853336

Address:shanghai
Sichuan JieYao Co., Ltd.

Contact:+86-838-5655598

Address:Guanghan Nanfeng Industrial Zone
Quhua Zhongxing Refrigeration Technology Co.,Ltd.

Contact:+86-5708886618

Address:318 Bulding 2, No.866 Quhua Rd.,Kecheng District
Hangzhou Eastbiopharm Co.,Ltd.

Contact:+86-571-88931780

Address:Hangzhou,China
GenicBio Limited

Contact:+86-(0)21-3770 9035

Address:Room 301, Building 2, Meijiabang Road 1508, Shanghai China

Relevant to this article

Unexpected pathway of the reaction of N-[(β-halogeno-α-tosyl) alkyl]ureas with β-oxoester enolates. Synthesis of ethyl 5-ureido-4,5-dihydrofuran-3-carboxylates and N-carbamoylpyrrole-3-carboxylates

Doi:10.1016/j.tetlet.2010.10.162
(2011)
Synthesis, cytotoxic evaluation, and DNA binding of novel thiazolo[5,4-b]quinoline derivatives

Doi:10.1016/j.bmc.2007.10.084
(2008)
Enantioselective cyanoformylation of aldehydes using a recyclable dimeric cinchonidine ammonium salt as an organocatalyst

Doi:10.1016/j.tetasy.2008.01.011
(2008)
Preparation of optically active 1,2-diol monotosylates by enzymatic hydrolysis

Doi:10.1055/s-2008-1032047
(2008)
Nucleosides. XXXIX. 2'-deoxy-2'-fluorocytidine, 1-beta-D-arabinofuranosyl-2-amino-1,4(2H)-4-iminopyrimidine, and related derivatives.

Doi:10.1021/jo01280a035
(1967)
Efficient and Recyclable Cobalt(II)/Ionic Liquid Catalytic System for CO2 Conversion to Prepare 2-Oxazolinones at Atmospheric Pressure

Doi:10.1002/cjoc.201900346
(2019)

Article Doi