Tetrahedron p. 12895 - 12902 (1997)
Update date:2022-07-30
Topics:
Ogawa, Akiya
Takami, Noriaki
Nanke, Taizoh
Ohya, Syoji
Hirao, Toshikazu
Sonoda, Noboru
A samarium/samarium diiodide mixed system successfully effects novel aminocyclopropanation and C-H insertion via the deoxygenation of amides. Styrenes undergo aminocyclopropanation by the reaction with aromatic amides, samarium metal, and samarium diiodide. Furthermore, the reaction of aliphatic amides with Sm/SmI2 in the presence of alkylbenzenes like toluene causes benzylic C-H insertion giving the corresponding phenylethylamine derivatives in good yields.
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