Tetrahedron p. 12895 - 12902 (1997)
Update date:2022-07-30
Topics:
Ogawa, Akiya
Takami, Noriaki
Nanke, Taizoh
Ohya, Syoji
Hirao, Toshikazu
Sonoda, Noboru
A samarium/samarium diiodide mixed system successfully effects novel aminocyclopropanation and C-H insertion via the deoxygenation of amides. Styrenes undergo aminocyclopropanation by the reaction with aromatic amides, samarium metal, and samarium diiodide. Furthermore, the reaction of aliphatic amides with Sm/SmI2 in the presence of alkylbenzenes like toluene causes benzylic C-H insertion giving the corresponding phenylethylamine derivatives in good yields.
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Doi:10.1002/ejoc.201500622
(2015)Doi:10.1002/anie.200704678
(2008)Doi:10.1021/jo702523u
(2008)Doi:10.1021/jo01117a608
(1956)Doi:10.1021/ja01501a055
(1960)Doi:10.1002/chem.200800328
(2008)
