Formation of a Homoleptic Unbridged Metal-Metal Bonded Isocyanide Dimer of Ruthenium(I) by Metal-Carbon Bond Cleavage in PF6: The X-ray Structure Determination of 2

DOI: 10.1039/c39850001340

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 1340 - 1341 (1985)

Update date:2022-07-29

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Authors:

Chalmers, Anthony A.

Liles, David C.

Meintjies, Elsie

Oosthuizen, Hester E.

Pretorius, Jan A.

Singleton, Eric

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Article abstract of DOI:10.1039/c39850001340

Refluxing PF6 in <(2)H6>acetone gives C8H13D and 2; an X-ray structure determination of 2 shows the cation to be an unbridged, metal-metal bonded dimer of ruthenium(I) containing eclipsed 2,6-dimethylphenyl isocyanide ligands.

Full text of DOI:10.1039/c39850001340

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