Formation of a Homoleptic Unbridged Metal-Metal Bonded Isocyanide Dimer of Ruthenium(I) by Metal-Carbon Bond Cleavage in PF6: The X-ray Structure Determination of 2

DOI: 10.1039/c39850001340

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 1340 - 1341 (1985)

Update date:2022-07-29

Topics:

Authors:

Chalmers, Anthony A.

Liles, David C.

Meintjies, Elsie

Oosthuizen, Hester E.

Pretorius, Jan A.

Singleton, Eric

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/c39850001340

Refluxing PF6 in <(2)H6>acetone gives C8H13D and 2; an X-ray structure determination of 2 shows the cation to be an unbridged, metal-metal bonded dimer of ruthenium(I) containing eclipsed 2,6-dimethylphenyl isocyanide ligands.

Full text of DOI:10.1039/c39850001340

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online

Products guided by the article

Product name:[Ru(1-5-η-C8H11)(CN-xylyl)3]PF6

Cas No:102279-82-3

R&D Labs maybe for 102279-82-3

Shanghai birch chemical technology co.,ltd

Contact:+86-21-54096810

Address:No.2588,Jungong Road,Shanghai,China
BOC Sciences

website:https://www.bocsci.com/

Contact:1-631-485-4226

Address:Ramsey Road
Cerametek Materials（ShenZhen）Co., Ltd.

Contact:+86-755-2324.2554

Address:A3-#9, YongChuan Street, Suite 501
Shanghai Mio Chemical Co., Ltd

Contact:0086 21- 64401188-622

Address:16 Floor NO.2 Jiefang Building, No. 4855 Dushi Road, 201100 Shanghai, P.R.China
Chengdu Green technology Co.,Ltd.

Contact:86-28-82608355

Address:C9 ,Economic Headquarters, Economic Development Zone, Chengdu.

Relevant to this article

New megastigmane glucosides from Excoecaria cochinchinensis Lour. var. cochinchinensis

Doi:10.1248/cpb.53.1600
(2005)
En route to archimedene: Total synthesis of C_3h-symmetric [7]phenylene

Doi:10.1021/ol027482z
(2003)
Identification of a novel oxazolidinone (U-100480) with potent antimycobacterial activity.

Doi:10.1021/jm950956y
(1996)
Synthesis of a chiral amino acid with bicyclo[1.1.1] pentane moiety and its incorporation into linear and cyclic antimicrobial peptides

Doi:10.1039/b702134h
(2007)
Doi:10.1021/jo01082a009
(1960)
An enantiospecific approach to tricyclic sesquiterpenes mayurone and thujopsenes

Doi:10.1021/jo0105484
(2001)

Article Doi