Formation of a Homoleptic Unbridged Metal-Metal Bonded Isocyanide Dimer of Ruthenium(I) by Metal-Carbon Bond Cleavage in PF6: The X-ray Structure Determination of 2

DOI: 10.1039/c39850001340

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 1340 - 1341 (1985)

Update date:2022-07-29

Topics:

Authors:

Chalmers, Anthony A.

Liles, David C.

Meintjies, Elsie

Oosthuizen, Hester E.

Pretorius, Jan A.

Singleton, Eric

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/c39850001340

Refluxing PF6 in <(2)H6>acetone gives C8H13D and 2; an X-ray structure determination of 2 shows the cation to be an unbridged, metal-metal bonded dimer of ruthenium(I) containing eclipsed 2,6-dimethylphenyl isocyanide ligands.

Full text of DOI:10.1039/c39850001340

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online

Products guided by the article

Product name:[Ru(1-5-η-C8H11)(CN-xylyl)3]PF6

Cas No:102279-82-3

R&D Labs maybe for 102279-82-3

Huludao Tianqi Shengye Chemical Co.,Ltd.

Contact:0086 429 2075777

Address:Area B,Shipbuilding Industry Park,Beigang District,Huludao City,Liaoning prov.,China
ZiBO KuoDing Trade company Ltd

website:http://www.sdzbkd.com

Contact:86-13361591822

Address:GongQingTuan road
Hubei Lansun Biochemical Pharmaceutical Co., Ltd

Contact:714-6395977

Address:No. 81 Pengcheng Avenue, economic and technological development zone, Huangshi City, Hubei Province,China
Tangshan Wisdom Trading Co.,Ltd

Contact:86 315 2222979

Address:No.41 BeiXinXi Road, Yangguang building 1-1102 , Tangshan, Hebei, China
Shandong Bolode Bio-Technology Co., LTD

Contact:+86-0531-58966870

Address:136 Jingyi Road,Huaiyin District,Jinan,Shandong,China

Relevant to this article

New megastigmane glucosides from Excoecaria cochinchinensis Lour. var. cochinchinensis

Doi:10.1248/cpb.53.1600
(2005)
En route to archimedene: Total synthesis of C_3h-symmetric [7]phenylene

Doi:10.1021/ol027482z
(2003)
Identification of a novel oxazolidinone (U-100480) with potent antimycobacterial activity.

Doi:10.1021/jm950956y
(1996)
Synthesis of a chiral amino acid with bicyclo[1.1.1] pentane moiety and its incorporation into linear and cyclic antimicrobial peptides

Doi:10.1039/b702134h
(2007)
Doi:10.1021/jo01082a009
(1960)
An enantiospecific approach to tricyclic sesquiterpenes mayurone and thujopsenes

Doi:10.1021/jo0105484
(2001)

Article Doi