Synthesis and substitution reactions of tris- and tetrakis(trimethyl phosphite)-substituted carbyne complexes of chromium, molybdenum, and tungsten

DOI: 10.1021/om00138a037

Source and publish data:

Organometallics p. 1504 - 1506 (1986)

Update date:2022-08-04

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Authors:

Mayr, Andreas

Dorries, Alison M.

McDermott, Gregory A.

Van Engen, Donna

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Article abstract of DOI:10.1021/om00138a037

Methods for the synthesis of X(CO)[P-(OMe)₃]₃M≡CPh (M = Cr, X = Br; M = Mo, W, X = Cl) and Cl[P(OMe₃)]₄M≡CPh (M = Mo, W) starting from the acyl complexes [NMe₄] [(CO)₅M-C(O)Ph] are described. Substitution of two or all four trimethyl phosphite ligands in Cl[P(OMe)₃]₄W=CPh by bis(diphenylphosphino)ethane is demonstrated. The crystal structure of Cl[P-(OMe)₃]₄Mo≡CPh is reported.

Full text of DOI:10.1021/om00138a037

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