Carbenoid Anion Behavior of Dilithio Derivatives of Thioacetal Alcohols. Stereochemistry and Mechanism of Ring Closures by Oxyanion-Facilitated CH Bond Insertion

DOI: 10.1021/ja00273a028

Source and publish data:

Journal of the American Chemical Society p. 3718 - 3725 (1986)

Update date:2022-07-29

Topics:

Authors:

Ritter, Robert H.

Cohen, Theodore

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/ja00273a028

Like other lithio derivatives of thioacetals bearing a second anionic site, dilithio derivatives of 3,3-, 5,5-, and 6,6-bis(phenylthio) alcohols decompose at or below ambient temperature to yield products ascribable to carbenoid intermediates.The 5,5-deri

Full text of DOI:10.1021/ja00273a028

Products guided by the article

Product name:trans-2-(phenylthio)-3,4,4a,5,6,7,8,8a-octahydro-2H-chromene

Cas No:102438-39-1

R&D Labs maybe for 102438-39-1

Zhejiang Newfine Industry Co.,Ltd.

Contact:+86-573-82262042

Address:No.225,Dongqing Road, garoms@163.com
ShanDong XinDa Chemical CO.,LTD(expird)

Contact:086-0311-87580543

Address:No.168, High Technology Development Zone Jinan Shandong China
Tianjin Jingye Fine Chemicals Co., Ltd.

Contact:+86-15722078107; +86-22-26911407

Address:Bohua Fine Chemicals Base of Petrochemical Industry Park, Nanhuan Road, Dagang District, Tianjin, 300271, P. R. China
New Forms

Contact:+31-24-3886056

Address:Binderskampweg 29 Unit 36
Fuxin Jintelai Fluorin Chemical Co., Ltd.

Contact:+86-0418-8229599

Address:, 7th Huagong Road, Fluorine industry development zone (Yimatu Town,Fumeng County),Fuxin City, Liaoning Province, China

Relevant to this article

Doi:10.1021/jo01064a023
(1961)
A convergent approach to the marine natural product eleutherobin: Synthesis of key intermediates and attempts to produce the basic skeleton

Doi:10.1039/b207800g
(2003)
Lewis acid catalyzed Claisen rearrangement: Regioselective synthesis of oxygen, nitrogen, and sulfur heterocycles

Doi:10.1139/V07-139
(2008)
Doi:10.1021/ja01648a046
(1954)
Total syntheses of the assigned structures of lituarines B and C

Doi:10.1021/ja078293k
(2008)
Studies of β-glycosylation via the N-iodosuccinimide procedure: Synthesis of the terminal disaccharide moiety of orthosomycins

Doi:10.1002/jlac.198619860609
(1986)

Article Doi