Carbenoid Anion Behavior of Dilithio Derivatives of Thioacetal Alcohols. Stereochemistry and Mechanism of Ring Closures by Oxyanion-Facilitated CH Bond Insertion

DOI: 10.1021/ja00273a028

Source and publish data:

Journal of the American Chemical Society p. 3718 - 3725 (1986)

Update date:2022-07-29

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Authors:

Ritter, Robert H.

Cohen, Theodore

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Article abstract of DOI:10.1021/ja00273a028

Like other lithio derivatives of thioacetals bearing a second anionic site, dilithio derivatives of 3,3-, 5,5-, and 6,6-bis(phenylthio) alcohols decompose at or below ambient temperature to yield products ascribable to carbenoid intermediates.The 5,5-deri

Full text of DOI:10.1021/ja00273a028

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