Enantioselective Synthesis of an Ent-Trichothecene

DOI: 10.1016/S0040-4020(01)80841-3

Source and publish data:

Tetrahedron p. 1651 - 1664 (1994)

Update date:2022-08-02

Topics:

Authors:

Gilbert, John C.

Selliah, Robert D.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4020(01)80841-3

A convergent route for the enantioselective synthesis of trichothecenes is described.A key step in the synthetic sequence is an Ireland-Claisen rearrangement that occurs with total facial selectivity and high diastereoselectivity.The relative stereochemis

Full text of DOI:10.1016/S0040-4020(01)80841-3

Products guided by the article

Product name:(2S,4S)-1-[1-[5-(tert-Butyl-dimethyl-silanyloxy)-2-methyl-cyclopent-1-enylmethoxy]-1-trimethylsilanyloxy-meth-(Z)-ylidene]-2-methoxy-4-methyl-cyclohexane

Cas No:1026335-14-7

R&D Labs maybe for 1026335-14-7

Beijing Apis Biotechnology Co., Ltd.

Contact:86-010-67856775-8551

Address:NO.4PUHUANGYU ROAD,FENTAI DISTRICT, BEIJING, CHINA
ZCIC INTERNATIONAL LTD

Contact:+86-512-56795332

Address:No227 Shuanglong Rd, Fenghuang, Zhangjiagang
Guangzhou Shiny Co., Ltd.

website:https://www.sinoshiny.com/products

Contact:+86-20-62802632;62802633

Address:Room 330 GIGCAS Building,No.511 Kehua Street,Tianhe District
Hangzhou innopharma technology Co,.Ltd.(expird)

Contact:+86-13388601988

Address:Room845,lixin building, moganshan road, hangzhou, china
Jiaxing Carry Bio-Chem Technology Co.,Ltd

website:http://www.carrybiotech.com

Contact:0573-82788958

Address:Add.Fl 3th, Pharm Vally,Kaichuang Rd, Xiuzhou District, Jiaxing, Zhejiang,314031,China

Relevant to this article

Kinetic study of electrochemically induced michael reactions of o-quinones with meldrum's acid derivatives. Synthesis of highly oxygenated catechols

Doi:10.1021/jo800115n
(2008)
Ring expansion-annulation strategy for the synthesis of substituted azulenes and oligoazulenes. 2. Synthesis of azulenyl halides, sulfonates, and azulenylmetal compounds and their application in transition-metal-mediated coupling reactions

Doi:10.1021/jo048698c
(2004)
Efficient Synthesis of Five Types of Heterocyclic Compounds via Intramolecular Elimination Using Ultrasound-Static Heating Technique

Doi:10.1002/asia.201800682
(2018)
Facile meso-BODIPY annulation and selective sensing of hypochlorite in water

Doi:10.1021/ol403405n
(2014)
Organic co-solvents restore the inherently high enantiomeric ratio of lipase B from Candida antarctica in hydrolytic resolution by relieving the enantiospecific inhibition of product alcohol

Doi:10.1016/S0957-4166(98)00273-0
(1998)
THE CONVERSION OF CARBOXYLIC ACIDS TO AMIDES VIA TIN(II) REAGENTS

Doi:10.1016/S0040-4039(00)73950-5
(1993)

Article Doi