Enantioselective Synthesis of an Ent-Trichothecene

DOI: 10.1016/S0040-4020(01)80841-3

Source and publish data:

Tetrahedron p. 1651 - 1664 (1994)

Update date:2022-08-02

Topics:

Authors:

Gilbert, John C.

Selliah, Robert D.

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Article abstract of DOI:10.1016/S0040-4020(01)80841-3

A convergent route for the enantioselective synthesis of trichothecenes is described.A key step in the synthetic sequence is an Ireland-Claisen rearrangement that occurs with total facial selectivity and high diastereoselectivity.The relative stereochemis

Full text of DOI:10.1016/S0040-4020(01)80841-3

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