Tetrahedron Letters p. 3989 - 3992 (1993)
Update date:2022-08-03
Topics:
Hayward, Cheryl M.
Fisher, Matthew J.
Yohannes, Daniel
Danishefsky, Samuel J.
Specific lactonization of a TBS ether followed by iodinative scission of a γ-lactol are the key elements of a strategy for maintaining continuous chemical distinction between the latent C34 and C32 hydroxyl groups of starting material 3 en route to 14, the C28-C42 fragment of rapamycin.
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