PALLADIUM-CATALYZED ADDITION REACTION OF OLEFINS, CARBON TETRACHLORIDE AND CARBON MONOXIDE IN ALCOHOLS TO GIVE 2-ALKYL-4,4,4-TRICHLOROBUTANOATES

DOI: 10.1016/S0040-4020(01)96745-6

Source and publish data:

Tetrahedron p. 5003 - 5006 (1985)

Update date:2022-07-29

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Authors:

Tsuji, Jiro

Sato, Koji

Nagashima, Hideo

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Article abstract of DOI:10.1016/S0040-4020(01)96745-6

Pd(OAc)2 combined with PPh3 is good catalyst for the addition reaction of CCl4 and CO to olefins in ethanol to afford ethyl 2-alkyl-4,4,4-trichlorobutanoates.The esters were obtained in satisfactory yields when the reaction was carried out at 50 deg C in

Full text of DOI:10.1016/S0040-4020(01)96745-6

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