Organometallics p. 1903 - 1906 (1986)
Update date:2022-07-30
Topics:
Anderson, Gordon K.
Cleavage of [Pt2(μ-Cl)2Ph2(PPh3)2] with TlC5H5 produces [Pt(η5-C5H5)Ph(PPh3)], but in low yield. Reaction of [Pt(η1-C5H5)Ph(cod)] with PPh3 in THF solution gives [Pt(η1:η2-C8H 12·C5H5)Ph(PPh3)] (1) in which the cyclopentadienyl and cyclooctadiene moieties are coupled. In ether 1 and [Pt(η5-C5H5)Ph(PPh3)] are both formed. Treatment of [Pt(η1-C5H5)Ph(cod)] with dppe or appe in ether solution results in displacement of cyclooctadiene, but the reaction with dppe in THF yields [Pt(η1-C5H5)Ph(dppe)] and a coupling product. The products are characterized by elemental analysis and by 1H, 13C{1H}, and 31P{1H} NMR spectroscopy.
Contact:+86-571-86025531 / 86024803
Address:1218-24 Guangyin Mansion,42 Fengqi East Road
Suzhou Sibian Chemical Technology Co., Ltd
website:http://www.sibianpharm.com
Contact:+8618169181984,+8618013186906
Address:Room1404,BuildingA,Jiabao Square No.323 Baodai East Road,Wuzhong District,Suzhou Jiangsu China (215128)
website:http://www.sigmaaldrich.com
Contact:800 558-9160
Address:Industriestrasse 25CH-9471 Buchs SGSwitzerland
Shandong Zhongcheng Barium Salt Co., Ltd
Contact:+86-15725732638
Address:No.29 baoxi road, hi-tech zone, zibo, shandong
Winchem Industrial Co. Ltd.(expird)
Contact:86-574-83851061 86-574-87083208
Address:Room 905, No.3 Building,East Business Center, 456 Xingning Road, Ningbo City,China
Doi:10.1021/jo020146b
(2002)Doi:10.1021/ic701343s
(2008)Doi:10.1016/j.bmc.2008.04.007
(2008)Doi:10.1016/j.tetlet.2008.04.086
(2008)Doi:10.1021/ja01467a024
(1961)Doi:10.1021/jo00370a016
(1986)
