FRAGMENTATION OF 1,3-DITHIOLANE-DERIVED SULFUR YLIDES. A CONVENIENT THIOALDEHYDE SYNTHESIS

DOI: 10.1016/S0040-4039(00)95011-1

Source and publish data:

Tetrahedron Letters p. 5265 - 5268 (1985)

Update date:2022-08-05

Topics:

Authors:

Schaumann, Ernst

Ruhter, Gerd

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Article abstract of DOI:10.1016/S0040-4039(00)95011-1

S-Ylides 10, which are generated by regiospecific deprotonation of 1,3-dithiolanium salts 9 with electron-withdrawing groups in the 4,5 positions, fragment under mild conditions to generate thioaldehydes 12.

Full text of DOI:10.1016/S0040-4039(00)95011-1

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