Stereochemistry of Reaction of a Phosphonamidic Chloride with t-Butylamine

DOI: 10.1039/c39850001394

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 1394 - 1395 (1985)

Update date:2022-07-30

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Authors:

Freeman, Sally

Harger, Martin J. P.

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Article abstract of DOI:10.1039/c39850001394

Both diastereoisomers of t-BuP(O)(Cl)NHR give the same mixture (55/45) of the diastereoisomers of t-BuP(O)(NHt-Bu)NHR on reaction with t-BuNH2 in dilute MeCN solution, but some stereospecificity is seen at higher amine concentrations.

Full text of DOI:10.1039/c39850001394

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