Carbene and Silicon Routes toward a Simple Nitrile Ylide. Spectroscopic, Kinetic, and Chemical Characterization

DOI: 10.1021/jo00222a053

Source and publish data:

Journal of Organic Chemistry p. 4415 - 4417 (1985)

Update date:2022-07-30

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Authors:

Turro, Nicholas J.

Cha, Yuan

Gould, Ian R.

Padwa, Albert

Gasdaska, John R.

Tomas, Miguel

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Article abstract of DOI:10.1021/jo00222a053

The generation and characterization of methyl nitrile ylide photochemically by addition of singlet methylene to acetonitrile and chemically from silylthioimidate and subsequent dipolar cycloaddition are carried out.

Full text of DOI:10.1021/jo00222a053

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