Tetrahedron p. 961 - 974 (1986)
Update date:2022-09-26
Topics:
Ohno, Atsuyoshi
Kashiwagi, Masanori
Ishihara, Yuji
Ushida, Satoshi
Oka, Shinzaburo
NAD(P)H/NAD(P)+ and related compounds have intrinsic chirality against the axis along the C3-Ccarbonyl single bond.A model compound which has a stable conformation with respect to this chirality was synthesized and the conformational relationship between the carbonyl dipole and the reacting hydrogen was studied.It has been concluded that there is a relationship between conformations of these groups both in reduction and in oxidation provided the substrate is a neutral species.The result is discussed in relation with the hypothesis proposed previously on the basis of quantum chemical calculations.
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Doi:10.1246/bcsj.59.1915
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(1938)Doi:10.1016/S0040-4039(00)98267-4
(1985)Doi:10.1080/00397910802029349
(2008)Doi:10.1016/j.bmcl.2009.09.014
(2009)Doi:10.1021/ja00286a024
(1986)
