Journal of Organic Chemistry p. 4548 - 4553 (1986)
Update date:2022-08-05
Topics: Nucleophile Reduction Aromatic hydrocarbons Aryl Halide Photocatalyst Carboxylation Reductive photocarboxylation Radical intermediate
Tazuke, Shigeo
Kazama, Shingo
Kitamura, Noboru
Photoirradiation of aromatic hydrocarbons such as phenanthrene, anthracene, or pyrene in the presence of an amine and carbon dioxide in dipolar aprotic solvents resulted in reductive carboxylation of the hydrocarbon.The reaction was considered to proceed
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