Regiospecific Generation and Alkylation of γ-Oxo α-Ester Enolates. Application to the Synthesis of Polycyclopentanoids

DOI: 10.1021/jo00377a001

Source and publish data:

Journal of Organic Chemistry p. 1 - 10 (1987)

Update date:2022-08-03

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Authors:

Marino, Joseph P.

Laborde, Edgardo

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Article abstract of DOI:10.1021/jo00377a001

A new strategy for <3 + 2> annulation utilizes the combination of a three-carbon synthon in the form of a γ-oxo α-ester enolate with a two-carbon Michael acceptor.The enolate synthon is derived from the fluoride-induced desilylation of 2-(silyloxy)cyclopr

Full text of DOI:10.1021/jo00377a001

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