Regiospecific Generation and Alkylation of γ-Oxo α-Ester Enolates. Application to the Synthesis of Polycyclopentanoids

DOI: 10.1021/jo00377a001

Source and publish data:

Journal of Organic Chemistry p. 1 - 10 (1987)

Update date:2022-08-03

Topics:

Authors:

Marino, Joseph P.

Laborde, Edgardo

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/jo00377a001

A new strategy for <3 + 2> annulation utilizes the combination of a three-carbon synthon in the form of a γ-oxo α-ester enolate with a two-carbon Michael acceptor.The enolate synthon is derived from the fluoride-induced desilylation of 2-(silyloxy)cyclopr

Full text of DOI:10.1021/jo00377a001

Products guided by the article

Product name:1-Pentalenecarboxylic acid, 1,2,4,5,6,6a-hexahydro-5,5-dimethyl-3-(phenylthio)-, ethyl ester, trans-

Cas No:105619-73-6

R&D Labs maybe for 105619-73-6

EGBERT CORPORATION

Contact:+86 18616952870

Address:Area
ZHEJIANG JIANYE CHEMICAL CO.,LTD.

Contact:86-571-64149273,64149234

Address:No. 48, Fuxi Road, Meicheng Town
Shanghai Coupling Pharmaceutical R&D Co., Ltd.(expird)

Contact:+86 021 50106671

Address:403 Room No.4 Buiding, No. 526 Ruiqing Road, Shanghai Zhangjiang Hi-Tech Park
SPRING CHEMICAL INDUSTRY CO.,LTD

Contact:86-187-66672125

Address:linchi industry park.zouping
Chemieliva Pharmaceutical Co., Ltd.

website:http://www.chemieliva.com

Contact:+86-23-67770219

Address:99 Longhua Road, Yubei District, 401147, Chongqing, China Email: sales@chemieliva.com Tel:0086-23-67770219 Fax: 0086-23-67770220 Attn: Andy Huang

Relevant to this article

1,5-Disubstituted indole derivatives as selective human neuronal nitric oxide synthase inhibitors

Doi:10.1016/j.bmcl.2011.07.022
(2011)
Rapid access to 3-(N-substituted)-aminoquinolin-2(1H)-ones using palladium-catalyzed C-N bond coupling reaction

Doi:10.1016/j.tet.2007.07.085
(2007)
Octahedral gyroscope-like molecules with M(CO)₃(X) rotators encased in three-spoked diphosphine stators: Syntheses by alkene metathesis/hydrogenation sequences, structures, dynamic properties, and reactivities

Doi:10.1021/om700625u
(2007)
Doi:10.1016/0040-4020(78)88411-7
(1978)
A Study of the Interconverison Between 3,4-Dihydro-4-formyl-2-hydroxy-2H-benzopyran and 2,3,3a,8a-Tetrahydro-2-hydroxyfuro<2,3-b>benzofuran Moieties, and its Application to a Formal Synthesis of (+/-)-Aflatoxin B1

Doi:10.1016/S0040-4020(01)90487-9
(1994)
Synthesis and absolute configuration of (-)-serantrypinone

Doi:10.1016/j.tetlet.2007.08.013
(2007)

Article Doi