
Journal of Organic Chemistry p. 312 - 314 (1987)
Update date:2022-08-04
Topics:
Reich, Hans J.
Holtan, Ronald C.
Borkowsky, Samuel L.
The addition of a number of organometallic reagents to α-phenylthio silyl ketones proceeds with good to excellent diastereoselectivity.The products undergo Brook rearrangement and fragmentation to enol silyl ethers with, in most cases, excellent stereoche
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