1-Aza-1,3-bis(triphenylphosphoranylidene)propane: A Novel =CHCH2N= Synthon

DOI: 10.1021/jo00095a034

Source and publish data:

Journal of Organic Chemistry p. 4551 - 4555 (1994)

Update date:2022-07-29

Topics:

Authors:

Katritzky, Alan R.

Jiang, Jinlong

Steel, Peter J.

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Article abstract of DOI:10.1021/jo00095a034

1-Aza-1,3-bis(triphenylphosphoranylidene)propane (3), prepared in situ by the reaction of 1-<<(triphenylphosphoranylidene)amino>methyl>benzotriazole (betmip, 4) with methylidenetriphenylphosphorane followed by treatment with butyllithium, enables convenient preparations of 3H-2-benzazepine (7), 2,3-diarylpyrroles 8, and primary allylamines 12 and 13.

Full text of DOI:10.1021/jo00095a034

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