ON THE COMMUNICATION OF CHIRALITY FROM FURANOSE AND PYRANOSE RINGS TO MONOSACCHARIDE SIDE CHAINS: ANOMALOUS RESULTS IN THE GLUCOSE SERIES

Article abstract of DOI:10.1016/S0040-4020(01)90570-8

The reactions of allyltrimethylsilane with dialdose derivatives occur, under catalysis by boron trifluoride etherate or titanium tetrachloride, with high stereoselectivity, thereby providing simple routes to the corresponding allyl carbinols.The sense of