Journal of Organic Chemistry p. 1013 - 1016 (1987)
Update date:2022-08-04
Topics:
Imi, Katsuharu
Yanagihara, Naoto
Utimoto, Kiitiro
Reaction of cyanotrimethylsilane with oxiranes under the catalytic action of Lewis acids Pd(CN)2, SnCl2, or Me3Ga affords 2-trimethylsiloxy isocyanides by regio- and stereoselective attack of isocyanide on the more substituted carbon.The reaction mediated by aluminium alkoxides gives predominantly 3-trimethylsiloxy nitriles by the selective attack of cyanide on the less substituted carbon.
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