Expeditious, Stereocontrolled Syntheses of Racemic and Natural Brasilenol through Intramolecular Asymmetry Transfer. Absolute Stereochemistry of Brasilenol

DOI: 10.1021/jo00382a042

Source and publish data:

Journal of Organic Chemistry p. 1169 - 1170 (1987)

Update date:2022-07-30

Topics:

Authors:

Greene, Andrew E.

Serra, A. Aarao

Barreiro, Eliezer J.

Costa, Paulo R. R.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/jo00382a042

Brasilenol, a marine metabolite, has been efficiently synthesized in both racemic and natural forms through the use of a highly selective palladium-catalyzed double bond migration.

Full text of DOI:10.1021/jo00382a042

Products guided by the article

Product name:(3R,4S)-3-But-3-enyl-4-isopropyl-cyclohexanone

Cas No:106862-52-6

R&D Labs maybe for 106862-52-6

Shanghai Egoal Chemical Co.,Ltd

Contact:+86-21-50333091

Address:Yangming Garden Square 3,YangGao North Road 1188, Pudong New District, Shanghai
NANCHANG QINZHI SCI&TEC.CO.,LTD(expird)

Contact:+86-13687004106

Address:Hero South Road,Hero Zone,Nanchang,Jiangxi,China
Jinan Baozhao Pharmaceutical Co., Ltd

Contact:0086-531-86397156 82371858 82371868

Address:Huaneng Road, Jinan, Shandong ,China
Shanghai Demand Chemical Co., ltd，China

Contact:86-021-55237578/55239122

Address:Room 3H, No.578, Yingkou Road, Yangpu District, Shanghai, China
Jiaxing Anrui Material Technology Co., Ltd.

Contact:86-573-82651652 13305832579

Address:Room 407, Technology Building, 1369 Chennan Road, Jiaxing City, Zhejiang, China

Relevant to this article

[1,5]-hydride transfer/cyclizations on alkynyl fischer carbene complexes: Synthesis of 1,2-dihydroquinolinyl carbene complexes and cascade reactions

Doi:10.1002/anie.200802268
(2008)
Synthesis and Base-Induced Methylation Reactions of cis-7a-Hydroxy-3a-(phenylsulfenyl)-3a,4,5,6,7,7a-hexahydro-4-indanone

Doi:10.1021/jo00383a020
(1987)
A concise approach to the polycyclic scaffold of frondosin D

Doi:10.1021/jo800682n
(2008)
PREPARATION AND PYROLYSIS OF SUBSTITUTED ETHANOANTHRACENES - A GENERAL SYNTHESIS OF 2,3-DISUBSTITUTED ANTHRACENES

Doi:10.1016/S0040-4020(01)87549-9
(1986)
Enzymatic synthesis of novel feruloylated lipids and their evaluation as antioxidants

Doi:10.1007/s11746-009-1496-y
(2010)
Invisible photochromism of diarylethene derivatives

Doi:10.1039/b804137g
(2008)

Article Doi