Expeditious, Stereocontrolled Syntheses of Racemic and Natural Brasilenol through Intramolecular Asymmetry Transfer. Absolute Stereochemistry of Brasilenol

DOI: 10.1021/jo00382a042

Source and publish data:

Journal of Organic Chemistry p. 1169 - 1170 (1987)

Update date:2022-07-30

Topics:

Authors:

Greene, Andrew E.

Serra, A. Aarao

Barreiro, Eliezer J.

Costa, Paulo R. R.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/jo00382a042

Brasilenol, a marine metabolite, has been efficiently synthesized in both racemic and natural forms through the use of a highly selective palladium-catalyzed double bond migration.

Full text of DOI:10.1021/jo00382a042

Products guided by the article

Product name:(3R,4S)-3-But-3-enyl-4-isopropyl-cyclohexanone

Cas No:106862-52-6

R&D Labs maybe for 106862-52-6

wuxi leji biology technology co., LTD

website:http://www.lejibio.com/

Contact:18362718864

Address:The Nanyue Road No. 2, Yixing City, Jiangsu Province
CHINA MEHECO CORPORATION

Contact:+86-10-67147360/67107388

Address:No.18 Guangming Zhongjie, Chongwen District, Beijing, 100061, China
Chengdu D-Innovation Pharmaceutical Co., Ltd

Contact:86-28-85105536

Address:1001, B6, No.88 Keyuan South Road, Chengdu Hi-Tech Zone
Liaoyang Xinyou Chemical Products Co.,Ltd.

Contact:+86-419-5165433 13604191870

Address:Huishang Road6-1, Hongwei District, Liaoyang, Liaoning, China
Nanjing Fayekong Chemcial Co.,Ltd(expird)

Contact:86-25-58813444

Address:Rm 1503, Unit 1, Building 5, Zijinnanyuan, Nanjing, Jiangsu, China

Relevant to this article

[1,5]-hydride transfer/cyclizations on alkynyl fischer carbene complexes: Synthesis of 1,2-dihydroquinolinyl carbene complexes and cascade reactions

Doi:10.1002/anie.200802268
(2008)
Synthesis and Base-Induced Methylation Reactions of cis-7a-Hydroxy-3a-(phenylsulfenyl)-3a,4,5,6,7,7a-hexahydro-4-indanone

Doi:10.1021/jo00383a020
(1987)
A concise approach to the polycyclic scaffold of frondosin D

Doi:10.1021/jo800682n
(2008)
PREPARATION AND PYROLYSIS OF SUBSTITUTED ETHANOANTHRACENES - A GENERAL SYNTHESIS OF 2,3-DISUBSTITUTED ANTHRACENES

Doi:10.1016/S0040-4020(01)87549-9
(1986)
Enzymatic synthesis of novel feruloylated lipids and their evaluation as antioxidants

Doi:10.1007/s11746-009-1496-y
(2010)
Invisible photochromism of diarylethene derivatives

Doi:10.1039/b804137g
(2008)

Article Doi