OXIDATIVE COUPLING OF KETENE DITHIOACETALS WITH SILYLATED CARBON NUCLEOPHILES BY THE USE OF TRITYL TETRAFLUOROBORATE

DOI: 10.1246/cl.1986.755

Source and publish data:

Chemistry Letters p. 755 - 758 (1986)

Update date:2022-08-04

Topics:

Authors:

Hashimoto, Yukihiko

Mukaiyama, Teruaki

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1246/cl.1986.755

2-Alkenyl-1,3-dithiolan or dithian-2-ylium cations are yielded by hydride abstraction of cyclic ketene dithioacetals with trityl tetrafluoroborate.These cations react with silyl enol ethers or an allylsilane completely regioselectively to give the corresp

Full text of DOI:10.1246/cl.1986.755

Products guided by the article

Product name:1-(2-[1,3]Dithian-2-ylidene-cyclohexyl)-3,3-dimethyl-butan-2-one

Cas No:107026-78-8

R&D Labs maybe for 107026-78-8

Shanghai Longschem Co.,Ltd

Contact:021-36356756

Address:Room601,Building No.14,280 Yangcheng Road,Shanghai
Dalian RSD International Trade Co.,Ltd.(expird)

Contact:86-22-60875058 58610575

Address:Wantong International Areas, Hongqiao District, Tianjin, China.China
HENAN NEW BLUE CHEMICAL CO.,LTD

website:http://www.newbluechem.com

Contact:86-371-55170693/55170694

Address:Zhengzhou International Trade New Territory,Jinshui District,Zhengzhou ,China
Guangxi Bonger Pharmaceutical Co., Ltd

website:http://napo.lookchem.com/

Contact:+86-18817331185

Address:Donghai Industrial Zone, Tiandong Country,Guangxi,China
Zhejiang Hoshine Silicon Industry Co., Ltd.

Contact:86-573-89179966

Address:Zhapu Town, Pinghu City, Zhejiang, China

Relevant to this article

Uncatalysed intermolecular aza-Michael reactions

Doi:10.1016/j.crci.2012.11.001
(2013)
Rhodium(III)-Catalyzed Redox-Neutral C-H Annulation of Arylnitrones and Alkynes for the Synthesis of Indole Derivatives

Doi:10.1002/adsc.201500580
(2015)
Synthesis, crystal structure, theoretical calculation, spectroscopic and antibacterial activity studies of copper(II) complexes bearing bidentate schiff base ligands derived from 4-aminoantipyrine: Influence of substitutions on antibacterial activity

Doi:10.1016/j.molstruc.2021.129908
(2021)
Electrochemical Acceptorless Dehydrogenation of N-Heterocycles Utilizing TEMPO as Organo-Electrocatalyst

Doi:10.1021/acscatal.7b04137
(2018)
Synthesis of polycyclic alkaloid-type compounds by an N -acyliminium Pictet-Spengler/diels-alder sequence

Doi:10.1055/s-0030-1258057
(2010)
Preparation of Enantiomerically Pure Protected 4-Oxo-α-amino Acids and 3-Aryl-α-amino Acids from Serine

Doi:10.1021/jo00038a030
(1992)

Article Doi