7-Phosphanorbornene Derivatives as Precursors of Esters and Amides of Two-co-ordinate Thiophosphenous O-Acid

DOI: 10.1039/c39860000844

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 844 - 846 (1986)

Update date:2022-08-05

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Authors:

Quin, Louis D.

Szewczyk, Jerzy

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Article abstract of DOI:10.1039/c39860000844

Heating thiophosphinate O-esters and thiophosphinamides having the 7-phosphanorbornene framework results in elimination of fragments that are derivatives of thiophosphenous O-acid; they are trapped by cycloaddition with 2,3-dimethylbutadiene to form 2,5-d

Full text of DOI:10.1039/c39860000844

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