2-DIMETHYLAMINOMETHYL-3-TRIMETHYLSILYLMETHYL-1,3-BUTADIENE AS 2,2'-BIALLYL DIRADICAL SYNTHON. A NEW AND FACILE ENTRY TO 1,2-DIMETHYLENECYCLOHEXANES, AND AND RING SYSTEMS

Article abstract of DOI:10.1016/S0040-4039(00)84669-9

The title compound, prepared readily by the cross-coupling reaction of β-bromoallyltrimethylsilane and the Grignard reagent from β-bromoallyldimethylamine, is an effective reagent as 2,2'-biallyl diradical synthon to give <6.6> and <6.7) ring systems by t