Tetrahedron p. 2993 - 3002 (1986)
Update date:2022-09-26
Topics:
Whitesell, James K.
Bhattacharya, Apurba
Buchanan, Charles M.
Chen, H. H.
Deyo, Don
et al.
We recently communicated (J.K.Whitesell, A.Bhattacharya, D.A.Aguilar and K.Henke, J.Chem.Soc.Chem.Commun. 989 (1982)) a highly efficient and effective method for the control of absolute stereochemistry through asymmetric induction in the ene reaction the chiral glyoxylate 1 with alkenes.We now have accumulated sufficient information on this process in terms of both its mechanistic details as well as its scope and applicability to a variety of situations that warrants a more complete presentation of these reactions.
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