Journal of the American Chemical Society p. 4690 - 4698 (1987)
Update date:2022-08-04
Topics: Thermal
Hoeger, Carl A.
Johnston, Allen D.
Okamura, William H.
The antarafacial stereochemistry of the thermal <1,7>-sigmatropic hydrogen shift has been demonstrated.The substrates studied include the epimeric cis-isotachysterol analogues 1 and 4 and their stereospecifically 15α-deuterium-labelled derivatives 7 and 1
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