Synthesis of New Cyclic Sulfur Ylides 9-Alkyl-10-cyano-9-thiaphenanthrenes and Their Novel Addition Reactions with Acetylenic Electrophiles

DOI: 10.1021/jo00392a032

Source and publish data:

Journal of Organic Chemistry p. 3668 - 3673 (1987)

Update date:2022-08-04

Topics:

Authors:

Hori, Mikio

Kataoka, Tadashi

Shimizu, Hiroshi

Komatsu, Osamu

Hamada, Koji

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/jo00392a032

Novel cyclic sulfur ylides 9 alkyl-10-cyano-9-thiaphenanthrenes were synthesized in good yield by proton abstraction from the corresponding 10H-9-thiaphenanthrenium salts 4 with triethylamine in ethanol. 10-Cyano-9-methyl-9-thiaphenanthrene (5a) was treat

Full text of DOI:10.1021/jo00392a032

Products guided by the article

Product name:2-<1-cyano-2,4-bis(methoxycarbonyl)-2,4-cyclopentadien-1-yl>-2'-(methylthio)biphenyl

Cas No:109182-08-3

R&D Labs maybe for 109182-08-3

Jiacheng-Chem Enterprises Limited(expird)

Contact:86-571-86711508

Address:19 Floor, CIBC Holley International Building, No. 198,Wuxing Road, Hangzhou, China,310020
HANGZHOU FOREWIN PHARMA CO., LTD

Contact:+86-571-89053961

Address:hangzhou
Taizhou Sunny Chemical Co.,Ltd

Contact:+86-523-86920899 +86-13951172783

Address:No.11 Xingyuang road, Gaoyong Chemical Industry Park, Gaogang Jiangsu China
Suzhou Ryan Pharmachem Technology Co.,Ltd

Contact:+86-0512-68780025

Address:B-301,No.2 Taishan Road,Suzhou New District,Jiangsu,P.R. China
SHANGHAI BIOSUNDRUG CO.,LTD.

Contact:86-21-34622192，13917187091，21-34622765

Address:No. 500 Caobao Road Shanghai P.R China

Relevant to this article

RCAI-61, the 6′-O-methylated analog of KRN7000: its synthesis and potent bioactivity for mouse lymphocytes to produce interferon-γ in vivo

Doi:10.1016/j.tetlet.2008.09.074
(2008)
3,3′- and 4,4′-biphenylene-bridged subporphyrin dimers

Doi:10.1021/ol8023924
(2008)
Design, synthesis and antimicrobial activity of novel benzothiazole analogs

Doi:10.1016/j.ejmech.2013.02.027
(2013)
New polynitrogen materials based on fused 1,2,4-triazines

Doi:10.1055/s-2006-926242
(2006)
Synthesis and reactions of the first fluorine-containing 1,3-bis(trimethylsilyloxy)-1,3-butadienes

Doi:10.1055/s-0028-1083440
(2008)
A diaminocyclohexyl analog of SNS-032 with improved permeability and bioavailability properties

Doi:10.1016/j.bmcl.2008.09.073
(2008)

Article Doi