Stereoselective Intramolecular Iodoetherification of 4-pentene-1,3-diols: Synthesis of cis-2-(Iodomethyl)-3-hydroxytetrahydrofurans

DOI: 10.1021/jo00227a023

Source and publish data:

Journal of Organic Chemistry p. 4062 - 4072 (1987)

Update date:2022-08-05

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Authors:

Tamaru, Yoshinao

Hojo, Makoto

Kawamura, Shin-ichi

Sawada, Shuji

Yoshida, Zen-ichi

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Article abstract of DOI:10.1021/jo00227a023

Intramolecular iodoetherification of 4-pentene-1,3-diol and its monosubstituted derivatives, irrespective of the substitution pattern, provides cis-2-(iodomethyl)-3-hydroxytetrahydrofurans in high yields.The cis selectivity generally exceeds 95percent .So

Full text of DOI:10.1021/jo00227a023

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