Journal of Fluorine Chemistry p. 105 - 116 (1986)
Update date:2022-07-29
Topics:
Semisch, C.
Margaretha, P.
The photochemical behaviour of the title compound, newly synthesized from 2-trifluoromethylcyclohexanone by bromination/dehydrobromination sequence, is compared to that of 6-methyl-2-cyclohexenone.Both compounds behave similarly regarding photocyclodimerization and addition to 2-methylpropene.Higher yields of reduction (electron transfer) products from the trifluoromethyl- vs. the methyl enone are obtained in the irradiations in the presence of 2,3-dimethyl-2-butene or in propanol, respectively.
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