Haloalkyl Complexes of the Transition Metals IV. The Formation of a Cationic Ylide Complex of Platinum(II) from a Chloromethylplatinum(II) Complex and The Crystal Structures of cis-I (X= Cl or I)

DOI: 10.1016/0022-328X(86)80443-0

Source and publish data:

Journal of Organometallic Chemistry p. 255 - 268 (1986)

Update date:2022-08-03

Topics:

Authors:

Engelter, Carola

Moss, John R.

Nassimbeni, Luigi R.

Niven, Margaret L.

Reid, Gordon

Spiers, John C.

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Article abstract of DOI:10.1016/0022-328X(86)80443-0

The reactions of Pt(PPh3)4 and Pt(C2H4)(PPh3)2 with CH2ClI have been investigated.The product of the reaction of Pt(PPh3)4 with CH2ClI is the cationic ylide complex cis-, whereas the reaction of Pt(C2H4)(PPh3)2 gives the oxidative

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Full text of DOI:10.1016/0022-328X(86)80443-0

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Product name:PtCl(P(C₆H₅)3)2(CH₂P(C₆H₅)3)⁽¹⁺⁾*I^(1-)*CH₂Cl₂ = [PtCl(P(C₆H₅)3)2(CH₂P(C₆H₅)3)]I*CH₂Cl₂

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Article Doi

Haloalkyl Complexes of the Transition Metals IV. The Formation of a Cationic Ylide Complex of Platinum(II) from a Chloromethylplatinum(II) Complex and The Crystal Structures of cis-I (X= Cl or I)

DOI: 10.1016/0022-328X(86)80443-0

Source and publish data:

Authors:

Article abstract of DOI:10.1016/0022-328X(86)80443-0

Full text of DOI:10.1016/0022-328X(86)80443-0

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