Helvetica Chimica Acta p. 339 - 341 (1987)
Update date:2022-09-26
Topics:
Rudolph, Andreas
Margaretha, Paul
Agosta, William C.
Propargyl-alkyl biradical 12 generated by photodecarbonylation of title ketone 3 undergoes ring closure to cyclobutane 7 and to vinyl carbene 13, this latter intermediate rearranging to the 5-ethylidenecyclopentenes 8a and 8b.
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Doi:10.1016/j.tet.2018.03.026
(2018)Doi:10.1002/jhet.5570240226
(1987)Doi:10.1021/jo00234a017
(1987)Doi:10.1016/S0040-4039(02)01401-6
(2002)Doi:10.1246/bcsj.60.1457
(1987)Doi:10.1271/bbb.80171
(2008)