Tetrahedron Letters p. 217 - 220 (1987)
Update date:2022-07-29
Topics:
Akasaka, Takeshi
Ando, Wataru
Photosensitized oxygenation of adamantylidenecyclopropanes gave either the corresponding 4-methylene-1,2-dioxolane or lactone and cyclic ketone depending on the substituent on the cyclopropane ring.The results are rationalized in terms of initial formation of a perepoxide intermediate followed by that of an allylic cation-type zwitterion or a carbonyl oxide, respectively.
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Doi:10.1002/jhet.5570240141
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