REACTION OF SINGLET OXYGEN WITH METHYLENECYCLOPROPANES: FORMATION OF 4-METHYLENE-1,2-DIOXOLANES

DOI: 10.1016/S0040-4039(00)95690-9

Source and publish data:

Tetrahedron Letters p. 217 - 220 (1987)

Update date:2022-07-29

Topics:

Authors:

Akasaka, Takeshi

Ando, Wataru

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4039(00)95690-9

Photosensitized oxygenation of adamantylidenecyclopropanes gave either the corresponding 4-methylene-1,2-dioxolane or lactone and cyclic ketone depending on the substituent on the cyclopropane ring.The results are rationalized in terms of initial formation of a perepoxide intermediate followed by that of an allylic cation-type zwitterion or a carbonyl oxide, respectively.

Full text of DOI:10.1016/S0040-4039(00)95690-9

Products guided by the article

Product name:C₁₇H₂₄O₂

Cas No:110819-29-9

R&D Labs maybe for 110819-29-9

Ningbo Hi-tech Zone Nice-Synth Chemical Industry Ltd.

Contact:+86-(574)-81110986

Address:No. 1210, Building 3, Wante Business Centre, Hi-tech Zone, Ningbo
Dalian RSD International Trade Co.,Ltd.(expird)

Contact:86-22-60875058 58610575

Address:Wantong International Areas, Hongqiao District, Tianjin, China.China
SHANGHAI BIOSUNDRUG CO.,LTD.

Contact:86-21-34622192，13917187091，21-34622765

Address:No. 500 Caobao Road Shanghai P.R China
NINGBO YINLIANG FOREIGN TRADE CO., LTD.

Contact:+86-574-87834016 / 87898057

Address:23F NO.666JINYU ROAD,YINGZHOU DISTRICT,NINGBO.CHINA
Sichuan JieYao Co., Ltd.

Contact:+86-838-5655598

Address:Guanghan Nanfeng Industrial Zone

Relevant to this article

Reactions of 2-isocyanatobenzoyl chloride and 2-carbomethoxyphenyl isocyanate with 5-aminotetrazole

Doi:10.1002/jhet.5570240141
(1987)
Improved robust method for preparing optically active 3-alkyl-3-phenyl-1,4- dioxane-2,5-diones; A promising new chiral template

Doi:10.1055/s-0028-1083211
(2008)
Isolation, structure elucidation, and biological activity of virgineone from Lachnum virgineum using the genome-wide Candida albicans fitness test

Doi:10.1021/np800511r
(2009)
Enantioselective synthesis of 1,1,1-trifluoroalkan-2-ols by ruthenium- catalyzed hydrogenation

Doi:10.1016/S0040-4039(00)00643-2
(2000)
Synthesis of highly substituted 2-perfluoroalkyl quinolines by electrophilic iodocyclization of perfluoroalkyl propargyl imines/amines

Doi:10.1039/b815398a
(2009)
A reinvestigation of the synthesis of arsonolipids (2,3-diacyloxypropylarsonic acids)

Doi:10.1016/j.chemphyslip.2008.02.001
(2008)

Article Doi