Journal of the Chemical Society. Chemical communications p. 996 - 998 (1986)
Update date:2022-07-31
Topics:
Schmidt, Ulrich
Werner, Juergen
The synthesis of (+)- and (-)-homononactic acid was achieved in 6 steps and 4 steps respectively starting with the raction of 2-lithium-5-vinylfuran and (S)-(-)-1,2-epoxybutane; both enantiomers were used in the construction of the achiral macrolide antibiotic tetranactin by esterification and subsequent lactonisation with the thiolester of 3-cyano-4,6-dimethyl-2-thiopyridone.
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