STUDIES OF STEREOCHEMICAL CONTROL USING α-LITHIOSULFINYL CARBANIONS

DOI: 10.1016/S0040-4020(01)90591-5

Source and publish data:

Tetrahedron p. 3003 - 3012 (1986)

Update date:2022-07-30

Topics:

Authors:

Williams, David R.

Phillips, James G.

White, Franklin H.

Huffman, John C.

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Article abstract of DOI:10.1016/S0040-4020(01)90591-5

The stereoselectivity in reactions of α-lithiosulfinyl carbanions with aldehydes has been unambiguously established.Steric effects and intramolecular chelation of the associated cation are important factors contributing to the observed outcome.

Full text of DOI:10.1016/S0040-4020(01)90591-5

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