
Chemistry Letters p. 351 - 354 (1987)
Update date:2022-08-04
Topics:
Uchiyama, Harumi
Kawano, Mika
Katsuki, Tsutomu
Yamaguchi, Masaru
The Claisen rearrangement of ester enolates with appropriate metal ions bearing bulky cyclopentadienyl ligands was found to proceed through a boat-like transition state leading to the products with the different configuration from that expected from a chair-like transition state.
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Doi:10.1021/ja00432a067
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(1987)