Stereochemical course of hydroboration of highly hindered steroidal olefins. A ready synthesis of 14β- and 8α,14β-steroids

DOI: 10.1016/0039-128X(86)90084-X

Source and publish data:

Steroids p. 131 - 141 (1986)

Update date:2022-08-05

Topics:

Authors:

Anastasia

Allevi Allevi

Fiecchi Fiecchi

Oleotti Oleotti

Scala Scala

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/0039-128X(86)90084-X

Hydroboration of 5α-cholest-8-ene, 5α,14β-cholest-8-ene and 5α,14β-cholest-7-ene provides a simple route to oxygenated steroids with 14β- and 8α,14β- unnatural stereochemistry.

Full text of DOI:10.1016/0039-128X(86)90084-X

Products guided by the article

Product name:5α,14β-cholestan-15β-ol

Cas No:111136-44-8

R&D Labs maybe for 111136-44-8

H&Y International Group Ltd

Contact:+86-571-86491666

Address:SHI XIANG ROAD
MENGNA

Contact:18698110882

Address:1303 No2 building,LuoMa Garden,YongAn Road,Hexi District,Tianjin city
Shanghai Bosman Industrial Co., Ltd

Contact:86-21-63065878-8006

Address:Rm907, No.1611, North Sichuan Road, Hongkou District, Shanghai, 200080 China
JADECHEM NINGBO CO.,LTD.

Contact:+86-574-89075960

Address:#100 Xiang Yun Road, New High tech area, Ningbo, China
Tianjin Ingenochem Technology Co.,Ltd

Contact:+86-22-23677060

Address:Hitech Green Industry Park K2-9-602, Nankai district

Relevant to this article

An unexpected tandem enantioselective Michael addition/oxa-nucleophilic rearrangement reaction of β,γ-unsaturated α-keto esters catalyzed by cinchona alkaloids

Doi:10.1016/j.tetasy.2008.11.007
(2008)
Tricyanovinylalkynyl-metal complexes: Synthesis and some reactions

Doi:10.1039/b810720c
(2009)
Dynamic kinetic resolution of racemic α-sulfonylaldehydes via asymmetric transfer hydrogenation

Doi:10.1016/j.tetlet.2008.11.031
(2009)
ISOMERIZATION AND DESULFURIZATION OF ALLENE EPISULFIDES

Doi:10.1016/S0040-4039(00)95422-4
(1987)
A new synthetic route to 3-Oxo-4-amino-1, 2, 3-oxadiazole from the diazeniumdiolation of benzyl cyanide: Stable sydnone iminium N-Oxides

Doi:10.1021/jo802343k
(2009)
A new route to dithiocarbamates from tertiary N-methyl and N-benzylamines

Doi:10.1080/00397919208019304
(1992)

Article Doi