Stereochemical course of hydroboration of highly hindered steroidal olefins. A ready synthesis of 14β- and 8α,14β-steroids

DOI: 10.1016/0039-128X(86)90084-X

Source and publish data:

Steroids p. 131 - 141 (1986)

Update date:2022-08-05

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Authors:

Anastasia

Allevi Allevi

Fiecchi Fiecchi

Oleotti Oleotti

Scala Scala

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Article abstract of DOI:10.1016/0039-128X(86)90084-X

Hydroboration of 5α-cholest-8-ene, 5α,14β-cholest-8-ene and 5α,14β-cholest-7-ene provides a simple route to oxygenated steroids with 14β- and 8α,14β- unnatural stereochemistry.

Full text of DOI:10.1016/0039-128X(86)90084-X

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