A Novel 1,3-Dithiane-based Cyclopenta-annellation Procedure: Synthesis of the Rocaglamide Skeleton

DOI: 10.1039/c39870000025

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 25 - 27 (1987)

Update date:2022-08-03

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Authors:

Davey, Andrew E.

Taylor, Richard J. K.

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Article abstract of DOI:10.1039/c39870000025

A novel three carbon cyclopentanone annellation procedure, based on direct 1,3-dithiane lithiation followed by intramolecular carbonyl addition, has been employed in a synthetic approach to the anti-cancer compound, rocaglamide.

Full text of DOI:10.1039/c39870000025

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Product name:2-(2-Iodo-2-phenyl-ethyl)-[1,3]dithiane

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