SILA PUMMERER REARRANGEMENT IN HIGHLY STERICALLY HINDERED ORGANOSILICON COMPOUNDS: A NEW ROUTE TO BIS(TRIMETHYLSILYL)KETONE

DOI: 10.1016/S0040-4039(00)85379-4

Source and publish data:

Tetrahedron Letters p. 5985 - 5988 (1986)

Update date:2022-08-03

Topics:

Authors:

Ricci, Alfredo

Innocenti, Alessandro Degl'

Ancillotti, Monica

Seconi, Giancarlo

Dembech, Pasquale

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Article abstract of DOI:10.1016/S0040-4039(00)85379-4

The oxidation of the tris(trimethylsilyl)methylthio-methane with m-chloroperoxybenzoic acid, leads through a sila-Pummerer rearrangement occuring in unusually mild conditions, to bis(trimethylsilyl)ketone,

Full text of DOI:10.1016/S0040-4039(00)85379-4

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