Tetrahedron Letters p. 4407 - 4410 (1987)
Update date:2022-08-03
Topics:
Adam, Waldemar
Guenther, Erhard
Haessel, Peter
Platsch, Herbert
Wilson, R. Marshall
The 2,2-dimethyl substituted 1,3-diradicals 5a-c posses significantly shorter triplet lifetimes (τT) than the parent 1,3-cyclopentadiyl 3, which is being rationalized on the basis of changes in the "through-bond" coupling and thus singlet-triplet energy splitting between the radical sites.
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Doi:10.1016/S0040-4039(00)95882-9
(1987)Doi:10.1139/v87-369
(1987)Doi:10.1016/0040-4039(84)80007-6
(1984)Doi:10.1021/jm00397a027
(1988)Doi:10.1002/ejoc.201301020
(2013)Doi:10.1016/S0040-4039(00)95326-7
(1987)
