Cyclopentanoid Synthesis via the Intramolecular Trapping of Oxy-Cope Intermediates. Stereocontrolled Synthesis of the cis- and trans-Hydroazulene Skeleton

DOI: 10.1021/jo00234a029

Source and publish data:

Journal of Organic Chemistry p. 5640 - 5642 (1987)

Update date:2022-07-30

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Authors:

Sworin, Michael

Lin, Ko-Chung

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Article abstract of DOI:10.1021/jo00234a029

The <3,3>-sigmatropic rearrangement of C5-substituted oxy-Cope derivatives was examined.With halomethyl groups the reaction sequence is efficiently directed to cyclopentanoid ring formation.

Full text of DOI:10.1021/jo00234a029

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