TOTAL SYNTHESIS OF CEREBROSIDES: (2S,3R,4E)-1-O-β-D-GALACTOPYRANOSYL-N-(2'R AND 2'S)-2'-HYDROXYTETRACOSANOYLSPHINGENINE

Article abstract of DOI:10.1016/0008-6215(87)80219-7

Total synthesis of both (2S,3R,4E)-1-O-β-D-galactopyranosyl-N-(2'R)-2'-hydroxytetracosanoylsphingenine 23 and the (2'S) stereoisomer were performed in an unambigous way by employing either (2S,3R,4E)-N-(2'R)-2'-(tert-butyldiphenylsilyloxy)tetracosanoylpsh