MANGANESE (III) BASED OXIDATIVE FREE-RADICAL CYCLIZATIONS. 2. POLYCYCLIZATION REACTIONS PROCEEDING THROUGH TERTIARY CATIONS.

DOI: 10.1016/S0040-4039(01)81003-0

Source and publish data:

Tetrahedron Letters p. 841 - 844 (1987)

Update date:2022-08-04

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Authors:

Snider, Barry B.

Mohan, Raju

Kates, Steven A.

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Article abstract of DOI:10.1016/S0040-4039(01)81003-0

Oxidative cyclization of 5 with Mn(OAc)3.2H2O gives mainly the bicyclic products 7 and 8.On the other hand, oxidative cyclization of 16 and 17 gives mainly the lactones 18 and 20.These data suggest that oxidation of a monocyclic radical to a cation preced

Full text of DOI:10.1016/S0040-4039(01)81003-0

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