Journal of Organometallic Chemistry p. 261 - 278 (1992)
Update date:2022-08-05
Topics:
Senechal-Tocquer, M.-C.
Senechal, D.
Bihan, J.-Y. Le
Gentric, D.
Caro, B.
et al.
In basic media, aromatic hydrocarbons and benzylmethylethers complexed by Cr(CO)3 units are readily nitrosated at the benzylic position by tBuONO, giving rise to Z and E oximes and hydroximates in moderate to excellent yields.With the meta-xylene and isochromane complexes it is possible to obtain a dinitrosation.
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