UMPOLUNG IN ALLYLIC PHOSPHONATES. REGIOSELECTIVE REACTION OF ACETOXY ALLYLIC PHOSPHONATES WITH NUCLEOPHILES CATALYZED BY PALLADIUM(0) COMPLEX

DOI: 10.1016/S0040-4039(00)96004-0

Source and publish data:

Tetrahedron Letters p. 1897 - 1900 (1987)

Update date:2022-08-05

Topics:

Authors:

Zhu, Jingyang

Lu, Xiyan

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Article abstract of DOI:10.1016/S0040-4039(00)96004-0

Vinilyc phosphonates with functional groups can be synthesized regioselective by the reaction of acetoxy allylic phosphonates with soft carbon nucleophiles in the presence of bis(trimethylsilyl)acetamide (BSA) under palladium(0) catalysis with moderate to good yields.

Full text of DOI:10.1016/S0040-4039(00)96004-0

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