UMPOLUNG IN ALLYLIC PHOSPHONATES. REGIOSELECTIVE REACTION OF ACETOXY ALLYLIC PHOSPHONATES WITH NUCLEOPHILES CATALYZED BY PALLADIUM(0) COMPLEX

DOI: 10.1016/S0040-4039(00)96004-0

Source and publish data:

Tetrahedron Letters p. 1897 - 1900 (1987)

Update date:2022-08-05

Topics:

Authors:

Zhu, Jingyang

Lu, Xiyan

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4039(00)96004-0

Vinilyc phosphonates with functional groups can be synthesized regioselective by the reaction of acetoxy allylic phosphonates with soft carbon nucleophiles in the presence of bis(trimethylsilyl)acetamide (BSA) under palladium(0) catalysis with moderate to good yields.

Full text of DOI:10.1016/S0040-4039(00)96004-0

Products guided by the article

Product name:4-Pentenoic acid, 5-(diethoxyphosphinyl)-2-(phenylsulfonyl)-, methyl ester, (Z)-

Cas No:113201-10-8

R&D Labs maybe for 113201-10-8

SHANGHAI ARCADIA BIOTECHNOLOGY LTD.

Contact:+86-21-61353236

Address:SUITE 901, BUILDING WENSLI, 1378 LU JIA BANG RD, SHANGAHI 200011, P.R.CHINA
suzhou BetterBioChem Co., Ltd.

website:http://www.betterbiochem.com

Contact:+86-18013506594

Address:No. 8 Building, 18 nong, Xi Yingnan Road, Pudong, Shanghai,China
Purestar Chem Enterprise Co.,Ltd

website:http://www.purestarchem.com

Contact:05722157374

Address:no235.huanchengdong Rd
Synochem Ingredients Corp., Ltd.

Contact:+86-512-5636 2180

Address:Zhangjiagang Free Trade Zone
TIANJIN DONGRUXIANG MINERALS MARKETING CO.,LTD(expird)

Contact:22-58516360

Address:tianjin

Relevant to this article

One-pot synthesis of 2-imino-1,3-oxaselenolanes by reaction of isoselenocyanates with 2-bromoethanol

Doi:10.3987/COM-08-11525
(2009)
InX₃-catalyzed haloamidation of vinyl arenes: a facile synthesis of α-bromo- and α-fluoroamides

Doi:10.1016/j.tetlet.2008.12.090
(2009)
SYNTHESIS OF CATIONIC METALLOCYCLOPHANES WITH ARENE AND CYCLOPENTADIENYL LIGANDS

Doi:10.1016/0022-328X(87)87133-4
(1987)
Dehydrooligopeptides. XX. Unusual Peptide Bond Cleavage of Dehydrotripeptide Esters Containing α-Dehydroamino Acid Residue at P₂ by Using Papain

Doi:10.1246/bcsj.70.1427
(1997)
Synthesis and studies of some new fused/spiro heterocyclic compounds containing nitrogen and sulfur

Doi:10.1080/10426500701841821
(2008)
Mesoporous silica nanosphere supported ruthenium catalysts for asymmetric hydrogenation

Doi:10.1002/anie.200705656
(2008)

Article Doi