An Efficient Synthesis of 15-Oxigenated T-Type Spirovetivanes. Its Application to the Synthesis of (+/-)-Isolubimin

Article abstract of DOI:10.1246/cl.1987.651

(4RS,7RS)-11-Hydroxy-15-norsolavetivane, a versatile intermediate for the synthesis of all 15-oxygenated T-type spirovetivanes, has been synthesized with high stereoselectivity.The synthesis has also been applied to preparation of (+/-)-<8,8-(2)H2>isolubi