Synthetic Communications p. 691 - 701 (2009)
Update date:2022-09-26
Topics:
Wei, Zhen
Lan, Hong-Qiao
Zheng, Jian-Feng
Huang, Pei-Qiang
A concise enantiospecific synthesis of (S)-6,8-bis(methylsulfonyloxy)- octanoic acid (2), a ready precursor of (R)-(+)-α-lipoic acid (1), is reported. The key step of the synthesis is the coupling of the tosylate derived from (R)-malic acid with phenylpro
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