A Dual Regiocontrol in the Copper-catalysed Grignard Reaction with Primary Allylic Acetates

DOI: 10.1039/C39870000827

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 827 - 829 (1987)

Update date:2022-08-03

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Authors:

Baeckvall, Jan-E.

Sellen, Michael

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Article abstract of DOI:10.1039/C39870000827

The reaction of primary allylic acetates with Grignard reagents in the presence of catalytic amounts of Li2CuCl4 can be regiochemically controlled to give either α- or γ-substitution of the allylic acetoxy group.

Full text of DOI:10.1039/C39870000827

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