A Dual Regiocontrol in the Copper-catalysed Grignard Reaction with Primary Allylic Acetates

DOI: 10.1039/C39870000827

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 827 - 829 (1987)

Update date:2022-08-03

Topics:

Authors:

Baeckvall, Jan-E.

Sellen, Michael

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/C39870000827

The reaction of primary allylic acetates with Grignard reagents in the presence of catalytic amounts of Li2CuCl4 can be regiochemically controlled to give either α- or γ-substitution of the allylic acetoxy group.

Full text of DOI:10.1039/C39870000827

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online

Products guided by the article

Product name:Benzene, [(2-ethenylhexyl)thio]-

Cas No:113446-72-3

R&D Labs maybe for 113446-72-3

Chengdu Boon Stream Chemical Industry Co.,Ltd.

Contact:+86-28-83156758

Address:No.859,Dongzikou Road,Jinniu District,Chengdu,Sichuan,P.R.China
JIANGXI AIFEIMU TECHNOLOGY CO.，LTD

Contact:+86-570-6040289

Address:FINECHEMICAL PARK,ZIBU TOWN,WANNIAN COUNTY,JIANGXI PROV.,CHINA,ZIP
Hefei TNJ chemical industry co.,ltd

website:https://www.tnjchem.com

Contact:+86-551-65418695

Address:B911 Xincheng Business Center, Qianshan Road, Hefei Anhui China
Zhejiang Linhai Xinhua Chemicals Factory

Contact:0086-13661858911

Address:Xunqiao Development Zone, Linhai, Zhejiang, China
Chengdu Biopurify Phytochemicals Ltd.

website:http://www.phytopurify.com

Contact:+86-28-82633397

Address:2F,No.11 Building,No.388 Rongtaidadao CNSTP,Wenjiang Zone,Chengdu,Sichuan, China

Relevant to this article

Switchable supramolecular polymers from the self-assembly of a small monomer with two orthogonal binding interactions

Doi:10.1021/ja200941a
(2011)
Synthesis, characterization, anticancer activity, and QSAR-studies of some new tetrahydropyrimidines

Doi:10.1007/s00044-010-9481-4
(2011)
Synthesis of 6^A,6^X-Di-O-(p-tosyl)-γ-cyclodextrins and Their Structural Determination through Enzymatic Hydrolysis of 3^A,6^A;3^X,6^X-Dianhydro-γ-cyclodextrins

Doi:10.1021/jo00244a018
(1988)
Pyridine-derived VEGFR-2 inhibitors: Rational design, synthesis, anticancer evaluations, in silico ADMET profile, and molecular docking

Doi:10.1002/ardp.202100085
(2021)
Synthesis and α-blocking activity of some analogues of idazoxan

Doi:10.1016/0223-5234(87)90263-7
(1987)
Reaction of Ester Enolates with Nucleophiles. Stereocontrolled Formation of Ketone and Aldehyde Enolates

Doi:10.1021/jo00243a050
(1988)

Article Doi