REMOTE ELECTRONIC CONTROL IN THE LiAlH4 REDUCTION OF TRICYCLIC p-TOLYLSULFONYLMETHYL ENONES

DOI: 10.1016/S0040-4039(00)96308-1

Source and publish data:

Tetrahedron Letters p. 3147 - 3150 (1987)

Update date:2022-07-31

Topics:

Authors:

Klunder, A. J. H.

Crul, M. J. F. M.

Houwen-Claasen, A. A. M.

Kooy, M. G.

Zwanenburg, B.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4039(00)96308-1

The LiAlH4 reduction of 4-p-tolylsulfonylmethyl-oxatricyclo<5.2.1.0^2,6>decadienones 3 and 8 leads regioselectively and stereospecifically to exo-methylene tricyclodecenols 6 and 11.The sulfone function is essential for this bis-hydride reductio

Full text of DOI:10.1016/S0040-4039(00)96308-1

Products guided by the article

Product name:2-Cyclopenten-1-ol, 4-ethoxy-5-methylene-, cis-

Cas No:113728-78-2

R&D Labs maybe for 113728-78-2

Jinan Kaypharm Chemical Co.,Ltd

Contact:86-0531-86986780

Address:Room101,No189-2,Huayuan Road,Jinan City,Shandong Province
Shanghai Yingrui Biopharma Co., Ltd

Contact:021-3358 8661*8003

Address:shanghai
Changzhou Foreign Trade Corp

Contact:+86-519-86623222

Address:29F/D, 99 Yanling West Road, Changzhou, Jiangsu, China
Dezhou Longteng Chemical Co., Ltd.

website:http://www.sodium-methoxide.cn/

Contact:0086-18866052283

Address:Xinhua Industrial Zone, Dezhou City, Shandong Province, China
Suzhou Chiral Pharmaceuticals Co., Ltd.

Contact:86-0512-63197058

Address:Building A, No. 2358, Chang'an Road, Wujiang Science Park

Relevant to this article

Enantioselective route to 5-methyl-And 5,7-dimethyl-6,7-dihydro-sh- dibenz[c,e]azepine: Secondary amines with switchable axial chirality

Doi:10.1021/ol900333c
(2009)
A catalysis study of mesoporous MCM-41 supported Schiff base and CuSO₄·5H₂O in a highly regioselective synthesis of 4-thiazolidinone derivatives from cyclocondensation of mercaptoacetic acid

Doi:10.1016/j.cclet.2015.10.029
(2016)
N4-tetradentate dicarboxyamidate/dipyridyl palladium complexes as robust catalysts for the Heck reaction of deactivated aryl chlorides

Doi:10.1002/chem.200802144
(2009)
tert-Butyl isocyanide as a convertible reagent in Ugi reaction: Microwave-assisted preparation of 5,6-dihydropyrazolo[1,5-a]pyrazine-4,7-diones

Doi:10.1055/s-0028-108766
(2009)
(+/-)-4-tert-Butyl-3-cyano-1-(4-ethynylphenyl)-2,6,7-trioxabicyclo<2.2.2>octane: Synthesis of a Remarkably Potent GABA_A Receptor Antagonist

Doi:10.1021/jm00401a002
(1988)
Solid-state gas sensors developed from functional difluoroboradiazaindacene dyes

Doi:10.1002/chem.200801911
(2009)

Article Doi