SYNTHESE STEREOSPECIFIQUE DE CIS-PYRETHROIDES PAR VOIE CYCLOPROPENIQUE UTILISANT UN SYNTHON CARBANIONIQUE. II. ACCES AUX DERIVES CIS-CHRYSANTHEMIQUES ET CIS-PYRETHRIQUES.

DOI: 10.1016/S0040-4020(01)90022-5

Source and publish data:

Tetrahedron p. 853 - 858 (1987)

Update date:2022-08-05

Topics:

Authors:

Franck-Neumann, Michel

Miesch, Michel

Kempf, Hubert

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4020(01)90022-5

The photolysis of series of gem-dimethyl 4-carbomethoxy 3H-pyrazoles, obtained from a common carbanionic precursor (preceding article) leads to cyclopropenic esters.These can be hydrogenated to the corresponding cis-disubstituted cyclopropanes which are direct precursors of chrysanthemates, pyrethric esters and analogous halopyrethroids.

Full text of DOI:10.1016/S0040-4020(01)90022-5

Products guided by the article

Product name:(1R,3S)-3-(2-Methoxycarbonyl-allyl)-2,2-dimethyl-cyclopropanecarboxylic acid methyl ester

Cas No:113767-62-7

R&D Labs maybe for 113767-62-7

JIEJIE GROUP CO.,LTD.

Contact:+86 021-51698675

Address:1701, Jielong Plaza, No.618 Pingliang Rd, ShangHai,China
JIANGXI AIFEIMU TECHNOLOGY CO.，LTD

Contact:+86-570-6040289

Address:FINECHEMICAL PARK,ZIBU TOWN,WANNIAN COUNTY,JIANGXI PROV.,CHINA,ZIP
SINFACHEM LIMITED

Contact:86-25-84683399

Address:605, Phoenix Herui Plaza, No.389, South Taiping Road, Nanjing, China 210002
C-LAB Chemievermittlung GmbH

Contact:+49-9398-993127

Address:Untertorstr. 27
Zhenjiang Huayu I/E Co.,LTD

Contact:86-511-85210668 0511-85210668, 85210818, 85210898

Address:Yihai Garden E-902,NO.99 Daxi RD., Zhenjiang Jiiangsu ,China

Relevant to this article

SYNTHESIS OF PYRIDO<1,2-b><2,4>BENZODIAZEPIN-6(11H)-IMINES

Doi:10.1007/BF00475372
(1987)
Organoselenium Chemistry. Preparation and Reaction of 2,4,6-Tri-tert-butylbenzeneselenenic Acid

Doi:10.1021/jo00245a056
(1988)
1,2,3-Triarylpropenones as starting materials for 2-pyridinethiones

Doi:10.1002/recl.19871061102
(1987)
Synthesis and structures of triorganochalcogenium (Te, Se, S) dinitramides

Doi:10.1002/ejic.200800565
(2008)
Synthesis of γ-halogenated ketones via the Ce(IV)-mediated oxidative coupling of cyclobutanols and inorganic halides

Doi:10.1016/j.tetlet.2008.12.114
(2009)
METHYL 5-O-TERT-BUTYLDIPHENYLSILYL-2-DEOXY-D-THREO-PENTOFURANOSIDE; AN APPROACH TO THE SYNTHESIS OF 3'-SUBSTITUTED-2',3'-DIDEOXYNUCLEOSIDES INCLUDING 3'-AZIDO-3'-DEOXYTHYMIDINE AND OF 3'-SUBSTITUTED-2',3'-DIDEOXY-C-NUCLEOSIDES

Doi:10.1016/S0040-4039(00)95550-3
(1987)

Article Doi