Journal of the Chemical Society. Perkin transactions I p. 1095 - 1098 (1987)
Update date:2022-08-02
Topics:
Ishibashi, Hiroyuki
Sato, Tatsunori
Irie, Maki
Ito, Masae
Ikeda, Masazumi
Diethyl chloro(methylthio)methylphosphonate (3) reacted with arenes and alk-1-enes in the presence of a Lewis acid to give the Friedel-Crafts product (5) and the ene product (8), respectively.The Pummerer rearrangement product (4) derived from diethyl (methylsulphinyl)methylphosphonate (10) also reacted with alk-1-enes in trifluoroacetic acid to give the products (8).
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(1988)
